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Environmental Concerns in Leather Manufacture

Raw leather requires extensive washing to remove dirt, salt and organic matter. Lime and sulfides are used to dehair the skin. As a result, large amounts of toxic waste and chemicals are released into the water system causing environmental pollution.The skin is then de-limed and softened by enzymatic action. Again, on washing, ammonium sulfate, enzymes and some protein is released into the water.

The solution used for tanning the hide contains chromium sulfate salt and free acid. About 75 per cent of the chromium present combines with the hide. This chromium tanning process, though a major cause of environmental pollution, is popular because it enhances the physical and chemical properties of finished leather.

Environmental and health concerns have resulted in a number of initiatives to reduce the presence of chromium in the waste stream, improve fixation on the leather, recycle chromium from effluents, and use aluminium and titanium as alternatives. The step is the colouring and oiling of the leather to make it as soft or as firm as desired. Once again, many chemicals are used and about 90 percent of it is fixed to the leather. The spent solutions are mildly acidic, with a pH between 4 and 6.

The Indian government has numerous laws in place that effect the leather industry. Although compliance is low, State Pollution Control Boards have in the last few years ordered closures of, and imposed fines on hundreds of tanneries for pollution infractions. Common effluent plants have been set up by both Central and State governments in all areas of where large numbers of tanneries are located. Establishing and enforcing proper waste treatment is an essential proactive step for the export sector.

The typical waste streams for leather production are outlined in Table 3 which documents the results of a pilot project on cleaner production in a developing country's tannery. The costs of remedying the pollution problems and the payback period are quantified.

Summary of Recommended Pollution Prevention Opportunities

Unit operation Pollution prevention action and environmental/product auality benefit Cost Payback period
Chromium Tanning Recycle chrome tanning - decreases Chromium to less than 3 mg/l $20,000 (saves $60,000 per year) 4 months
Solvent Discharge Change to water-based lacquer finish decreases VOC usage by 60-90 per cent None To be determined
Water use Change to batch wastes - decreases water usage by 20-40 per cent None To be determined
Solid waste Save leather trimmings for reconstituted leather - decrease leather waste by 60-80 percent $10,000 To be determined
Sulfide waste Destroy sulfides by air oxidation - decreases sulfide waste by 95-98 percent $30,000 To be determined
Suspended solids Primary treatment - dresses suspended solids by 70-85 percent $100,000 To be determined
Sludge from Effluent Dry sludge for land application - allows disposal of sludge as fertilizer $20,000 To be determined


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AMBATTUR INDUSTRIAL ESTATE

When one mentions industry in Chennai, the Ambattur Industrial Estate comes instantly to mind. It is located about 15 kms from the city and 20 kms from the Airport. It is well connected by both suburban train and bus services.

Ambattur Industrial EstateSpread over an area of about 1,500 acres, the Ambattur Industrial Estate has 2,000 units of small, medium and large industries. All the industries together provide employment to about 2 lakh persons. Women constitute one third of the workforce employed in the various industries in Ambattur. The annual turnover from all units at Ambattur Industrial Estate is Rs. 2,000 crore, of which the export component alone is more than Rs. 500 crore.

The scope of industrial activity in Ambattur is far and varied. It includes Automobile components, Fabrication Units, Foundries / forge shops, Engineering products, garments, leather goods, rubber and plastic components, electrical equipment, tool rooms, machine tools, machine shops in the light to heavy range, Service Industries and metal finishings.

Author : Joseph Pradeep Raj R


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