Raw leather requires extensive washing to remove dirt, salt and
organic matter. Lime and sulfides are used to dehair the skin. As
a result, large amounts of toxic waste and chemicals are released
into the water system causing environmental pollution.The skin is
then de-limed and softened by enzymatic action. Again, on washing,
ammonium sulfate, enzymes and some protein is released into the
water.
The solution used for tanning the hide contains chromium sulfate
salt and free acid. About 75 per cent of the chromium present combines
with the hide. This chromium tanning process, though a major cause
of environmental pollution, is popular because it enhances the physical
and chemical properties of finished leather.
Environmental and health concerns have resulted in a number of initiatives
to reduce the presence of chromium in the waste stream, improve
fixation on the leather, recycle chromium from effluents, and use
aluminium and titanium as alternatives. The step is the colouring
and oiling of the leather to make it as soft or as firm as desired.
Once again, many chemicals are used and about 90 percent of it is
fixed to the leather. The spent solutions are mildly acidic, with
a pH between 4 and 6.
The Indian government has numerous laws in place that effect the
leather industry. Although compliance is low, State Pollution Control
Boards have in the last few years ordered closures of, and imposed
fines on hundreds of tanneries for pollution infractions. Common
effluent plants have been set up by both Central and State governments
in all areas of where large numbers of tanneries are located. Establishing
and enforcing proper waste treatment is an essential proactive step
for the export sector.
The typical waste streams for leather production are outlined in
Table 3 which documents the results of a pilot project on cleaner
production in a developing country's tannery. The costs of remedying
the pollution problems and the payback period are quantified.
Summary of Recommended Pollution Prevention
Opportunities
Unit operation
Pollution prevention action and environmental/product auality
benefit
Cost
Payback period
Chromium Tanning
Recycle chrome tanning - decreases Chromium
to less than 3 mg/l
$20,000 (saves $60,000 per year)
4 months
Solvent Discharge
Change to water-based lacquer finish decreases
VOC usage by 60-90 per cent
None
To be determined
Water use
Change to batch wastes - decreases water usage
by 20-40 per cent
None
To be determined
Solid waste
Save leather trimmings for reconstituted leather
- decrease leather waste by 60-80 percent
$10,000
To be determined
Sulfide waste
Destroy sulfides by air oxidation - decreases
sulfide waste by 95-98 percent
$30,000
To be determined
Suspended solids
Primary treatment - dresses suspended solids
by 70-85 percent
$100,000
To be determined
Sludge from Effluent
Dry sludge for land application - allows disposal
of sludge as fertilizer
$20,000
To be determined
AMBATTUR INDUSTRIAL ESTATE
When one mentions industry in Chennai, the Ambattur Industrial
Estate comes instantly to mind. It is located about 15 kms from
the city and 20 kms from the Airport. It is well connected by both
suburban train and bus services.
Spread
over an area of about 1,500 acres, the Ambattur Industrial Estate
has 2,000 units of small, medium and large industries. All the industries
together provide employment to about 2 lakh persons. Women constitute
one third of the workforce employed in the various industries in
Ambattur. The annual turnover from all units at Ambattur Industrial
Estate is Rs. 2,000 crore, of which the export component alone is
more than Rs. 500 crore.
The scope of industrial activity in Ambattur is far and varied.
It includes Automobile components, Fabrication Units, Foundries
/ forge shops, Engineering products, garments, leather goods, rubber
and plastic components, electrical equipment, tool rooms, machine
tools, machine shops in the light to heavy range, Service Industries
and metal finishings.